ACRYLAMIDE-SODIUM ACRYLATE RESIN

CAS: 25085-02-3 BOILER WATER ADDITIVE

**ACRYLAMIDE-SODIUM ACRYLATE RESIN** is a synthetic copolymer made from acrylamide and sodium acrylate monomers used primarily as a boiler water additive for steam systems in food processing and related industries. It is covered under specific US FDA food additive regulations that allow its use under controlled conditions for indirect food contact through steam generation.

What It Is

ACRYLAMIDE-SODIUM ACRYLATE RESIN is a high molecular weight copolymer formed by the copolymerization of acrylamide and sodium acrylate monomers. This type of resin belongs to the class of synthetic polymer substances characterized by long chains composed of repeating acrylamide and acrylate units. Its structure imparts properties typical of water-soluble anionic polymers, including hydrophilicity and scale-dispersing activity. In industrial and food processing settings, this resin functions as a boiler water additive that helps control corrosion and scale formation in steam systems that generate water vapor for indirect contact with food. Because it interacts with water treatment chemistry rather than the food itself, it is regulated as a secondary direct food additive under specific conditions outlined by the U.S. Food and Drug Administration (FDA). According to FDA listings, substances in this chemical class have designated allowed usage as boiler water additives, subject to technical specifications and residual monomer limits. The resin’s technical identity is tied to its CAS number and the array of synonyms used in chemical catalogs and regulatory inventories, which reflect its polymeric composition and anionic nature. Despite its designation as a food-related additive category, it is not a flavoring, nutrient, or direct ingredient in food products but rather plays a role in food processing equipment operation.

How It Is Made

The manufacturing of ACRYLAMIDE-SODIUM ACRYLATE RESIN typically involves controlled copolymerization of acrylamide and sodium acrylate monomers in aqueous solution under initiator-driven conditions. In broad terms, the production process begins with dissolving the monomers in water and adding a polymerization initiator, such as a free radical generator, to start the chain reaction. By adjusting reaction conditions like temperature, pH, and initiator concentration, manufacturers can influence the molecular weight and distribution of the resulting polymer chains. After polymerization is complete, the polymer solution may be neutralized, stabilized, and purified to meet specification requirements for its intended industrial use. The product may be isolated as an aqueous solution or dried into a powder or granule form for easier handling and storage. Quality control analyses assess properties such as viscosity, residual monomer content, and ionic composition to ensure consistency with technical performance standards. In the context of food-related boiler water additives, regulatory specifications often include limits on residual acrylamide monomer content to minimize potential exposure. These specifications are part of the conditions under which the additive is approved for use in steam systems that indirectly contact food. Because the resin is a synthetic polymer, its manufacture does not resemble natural biochemical synthesis but is instead rooted in industrial polymer chemistry and controlled reaction engineering.

Why It Is Used In Food

Although ACRYLAMIDE-SODIUM ACRYLATE RESIN is not incorporated into foods directly, it plays a role in the food industry by supporting steam generation systems used in food processing. In many food manufacturing facilities, steam is used for cooking, sterilization, blanching, and cleaning operations. To maintain efficient boiler operation and protect equipment from corrosion and mineral scale build-up, boiler water additives are introduced into the feedwater. This resin functions to help manage the chemistry of the water phase, mitigating deposits that can impair heat transfer and reduce equipment life. By controlling scale and corrosion, it contributes indirectly to consistent steam quality and reliable plant operations. The resin’s activity lies in its ability to interact with dissolved ions and inhibit the formation of problematic scale deposits. As a synthetic anionic polymer, it offers a balance of solubility and performance that supports these technical objectives. Its use under regulated conditions ensures that boilers produce steam safely without adversely affecting the quality of food processed with that steam. Steam treated with approved additives like this resin contacts food only indirectly, and the regulations governing its use focus on limiting residual components in boiler systems rather than dictating food formulation choices.

Adi Example Calculation

Because ACRYLAMIDE-SODIUM ACRYLATE RESIN does not have an established acceptable daily intake (ADI) value due to its indirect use as a boiler water additive, an illustrative ADI calculation is not applicable in this case. Typical ADI calculations involve identifying a no-observed-adverse-effect level (NOAEL) from toxicological studies for a substance intended for direct human ingestion and applying safety factors to derive a tolerable daily intake level. For substances evaluated through this process, the ADI represents an amount that could theoretically be ingested each day over a lifetime without appreciable health risk. Because this resin is used to treat boiler water and does not enter foods directly, and because its regulatory approval focuses on controlling residual monomer content rather than defining an ADI, constructing a hypothetical ADI for this resin would not align with how regulators assess its safety. Therefore, instead of demonstrating a calculation, it is more appropriate to note that compliance with regulatory provisions that limit residual monomers and restrict usage conditions is the primary mechanism ensuring safety for indirect contact applications.

Safety And Health Research

The safety evaluation of ACRYLAMIDE-SODIUM ACRYLATE RESIN centers on its intended use as a boiler water additive with indirect contact to food via steam, rather than consumption. Regulatory assessments focus on limiting residual monomer content, particularly acrylamide monomer, which has different hazard profiles when isolated. In its polymeric form within this resin, acrylamide units are part of long chains and the residual monomer content is tightly controlled as specified in regulatory listings, reflecting efforts to minimize potential exposure. Scientific research on polymers used as boiler water additives typically assesses chemical stability, breakdown products, and potential for residual monomer release under operational conditions, rather than direct toxicological endpoints associated with ingestion of the polymer itself. High molecular weight polymers like this resin are generally considered unlikely to be absorbed through the gastrointestinal tract if inadvertently present at trace levels, but specific safety studies may be limited due to the nature of their use in industrial water systems. Research attention in related chemical classes often involves environmental fate, worker handling exposure, and degradation behavior under extreme conditions, but not direct food safety endpoints because of the indirect nature of contact. As a result, safety narratives emphasize technical controls, compliance with regulatory limits on residual monomers, and adherence to boiler water management practices rather than consumer intake thresholds. Available regulatory information does not provide comprehensive toxicological values for this resin itself, and guidance in narrative contexts remains grounded in its regulated use and restrictions rather than detailed health studies.

Regulatory Status Worldwide

ACRYLAMIDE-SODIUM ACRYLATE RESIN is regulated in the United States as a secondary direct food additive under specific sections of the Code of Federal Regulations (CFR). Under 21 CFR 173.310, boiler water additives may be safely used in the preparation of steam that will contact food, and acrylamide-sodium acrylate resin is among the substances listed with defined limitations on residual monomer content, ensuring the compound is prepared from substances identified in the regulation and subject to prescribed conditions. The listing specifies that the resin should contain not more than a defined percentage of residual acrylamide monomer when used for this purpose, a provision that reflects regulatory attention to potential exposure. Other relevant sections include 21 CFR 172.710 and 21 CFR 173.5, which encompass related uses and polymer substance conditions, although these sections address broader categories or similar resins. The inclusion of this resin in these regulatory sections means that its use in U.S. food processing boiler systems is permitted when processors adhere to the technical and compositional conditions specified by the FDA. In other jurisdictions outside the United States, regulatory approaches to boiler water additives may vary and are generally governed by local food safety and equipment standards rather than ingredient-level approval lists. However, because this resin’s primary function relates to water-treatment chemistry and indirect food contact, it is less likely to be subject to the same food additive approval processes as direct food ingredients in international frameworks. As such, food industry operators using this resin outside the United States should consult applicable local regulations for indirect food contact substances and boiler water treatment standards.

Taste And Functional Properties

Because ACRYLAMIDE-SODIUM ACRYLATE RESIN is not an ingredient added directly to foods but rather used in boiler water systems, it does not contribute taste or flavor to food products. Its functional properties pertain to its role as a polymeric water-treatment additive. In aqueous environments, the copolymer’s anionic chains interact with dissolved minerals and scale-forming ions, helping to disperse them and reduce their tendency to precipitate on heat transfer surfaces. This dispersion activity supports more efficient heat exchange and reduces the frequency of mechanical cleaning or maintenance in steam generation systems. The resin’s solubility in water and stability under boiler conditions make it suitable for continuous or batch addition to boiler feedwater within specified technical limits. Its molecular structure, characterized by repeating acrylamide and acrylate units, promotes interaction with charged species in solution, contributing to scale management without affecting the sensory properties of foods processed with steam. Unlike direct food additives that influence taste, texture, or mouthfeel, boiler water additives are evaluated for their chemical stability, performance under high temperature and pressure, and compatibility with other boiler treatment chemistries. Because these polymers are engineered rather than derived from natural food components, their functional evaluation centers on engineering outcomes rather than culinary attributes.

Acceptable Daily Intake Explained

The concept of acceptable daily intake (ADI) is a regulatory tool used to express the amount of a substance that can be ingested daily over a lifetime without appreciable health risk. Because ACRYLAMIDE-SODIUM ACRYLATE RESIN is not a direct food ingredient but a boiler water additive with indirect contact via steam, there is no established ADI value specifically for this resin in food additive regulations. Instead, regulatory frameworks focus on limiting residual components such as acrylamide monomer within the resin itself, ensuring that potential exposure through boiler steam remains minimal. In the absence of an explicit ADI for this resin, narrative explanations of ADI center on general principles: an ADI is derived from toxicological studies that identify a no-observed-adverse-effect level (NOAEL) for a substance, which is then divided by safety factors to account for uncertainties. If a given substance were intended for direct ingestion, regulators would require comprehensive toxicological data to set an ADI. In this case, because the resin’s use is indirect and regulatory conditions limit residual monomer content, the ADI framework is less applicable. Instead, compliance with compositional and usage limitations specified by the FDA serves a similar protective function, ensuring that any potential exposure remains far below levels that might raise concern. This approach reflects the different evaluation pathways for indirect contact substances versus direct food ingredients, with narrative emphasis on the principles of minimizing exposure and controlling residual monomers rather than calculating a formal ADI.

Comparison With Similar Additives

When comparing ACRYLAMIDE-SODIUM ACRYLATE RESIN with other additives used in food processing support systems, it helps to differentiate based on function and contact nature. For example, corrosion inhibitors like neutralizing amines are another class of boiler water additives that protect metal surfaces from acid corrosion; these chemicals are also regulated for indirect contact through steam systems. Unlike the polymeric resin, neutralizing amines function by adjusting water pH and buffering acidic species. Another comparison could be scale dispersants such as polyphosphates, which mitigate mineral scale buildup in boiler systems; polyphosphates are low molecular weight anionic species with different interaction profiles compared to high molecular weight copolymers. In water treatment outside the food sector, organic polymers like polyacrylamides are used as flocculants to aggregate suspended solids in wastewater, but their regulatory assessment differs because they are not connected to food processing equipment. By contrast, direct food additives such as emulsifiers (e.g., lecithin) serve functional roles within the food matrix itself and are evaluated for sensory, rheological, and safety endpoints related to consumption. In each case, the comparison highlights that boiler water additives like the acrylamide-acrylate resin are evaluated and approved for a technical water-treatment function rather than for effects on taste, texture, or nutritional profiles in food products.

Common Food Applications Narrative

In modern food processing environments, steam plays a vital role in a range of unit operations such as blanching vegetables, cooking canned foods, pasteurization, sterilization, and cleaning-in-place procedures. Achieving consistent steam quality requires careful control of boiler water chemistry to prevent scale formation and corrosion that can compromise heat transfer efficiency and equipment integrity. ACRYLAMIDE-SODIUM ACRYLATE RESIN is used in these contexts as a boiler water additive that helps manage mineral deposits and protect system components. Steam treated with approved boiler additives contacts food indirectly, meaning the additive itself is not mixed into the food but instead influences the water chemistry of the boiler producing the steam. For example, in canning operations where steam is used to heat sealed containers, reliable boiler operation helps ensure uniform heating and product safety. In vegetable blanching operations, effective scale control contributes to consistent temperature profiles and reduces downtime for equipment maintenance. Although this resin does not appear on ingredient labels for finished food products, its use in supporting steam systems underscores the broad scope of chemical additives in the food industry, extending beyond direct food formulation to include critical processing aids. By conforming to regulatory requirements for indirect food contact, food processors can maintain efficient steam generation while adhering to safety standards that govern the substances allowed in boiler water. These technical contributions, although not visible to the consumer, support the reliable production of a wide range of packaged and prepared foods.

Safety & Regulations

FDA

  • Approved: True
  • Regulation: 21 CFR 173.310

EFSA

  • Notes: No specific EFSA authorization located for this indirect contact substance

JECFA

  • Notes: No specific JECFA evaluation for this resin located in JECFA database

Sources

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